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SAMDAILY.US - ISSUE OF OCTOBER 12, 2023 SAM #7989
SPECIAL NOTICE

99 -- TECHNOLOGY/BUSINESS OPPORTUNITY Water Softening Using Flow Through Electrode Capacitive Deionization

Notice Date
10/10/2023 1:42:17 PM
 
Notice Type
Special Notice
 
NAICS
221310 — Water Supply and Irrigation Systems
 
Contracting Office
LLNS � DOE CONTRACTOR Livermore CA 94551 USA
 
ZIP Code
94551
 
Solicitation Number
IL-13462
 
Response Due
11/10/2023 2:00:00 PM
 
Archive Date
11/25/2023
 
Point of Contact
Jared Lynch, Phone: 9254226667, Charlotte Eng, Phone: 9254221905
 
E-Mail Address
lynch36@llnl.gov, eng23@llnl.gov
(lynch36@llnl.gov, eng23@llnl.gov)
 
Description
Opportunity: Lawrence Livermore National Laboratory (LLNL), operated by the Lawrence Livermore National Security (LLNS), LLC under contract no. DE-AC52-07NA27344 (Contract 44) with the U.S. Department of Energy (DOE), is offering the opportunity to enter into a collaboration to further develop and commercialize its flow-through electrode capacitive deionization for water softening technology. Background: The current state of the art for water softening is ion exchange in columns packed with functionalized resin. The ion-exchange resins (IERs) work by adsorbing scale forming ions (calcium, magnesium) and replacing them with another ion, sodium, in the softened water. These resins must be periodically regenerated using large amounts of food grade salt, a consumable chemical that must be purchased.� Additionally, this water softening method introduces a high salt load into municipal sewer systems and water treatment plants. An alternative process is to use water desalination technology, such as reverse osmosis (RO). Reverse osmosis uses membranes that allow only water to pass through membranes easily while restricting the passage of contaminants. However, a RO membrane is non-selective; the membrane is capable of removing all the ions present in the water, but not a targeted �contaminant. This characteristic reduces the possible efficiency of using RO to treat water for specific trace contaminants such as magnesium and calcium. A promising method for water softening may be Capacitive DeIonization (CDI), which has the potential to be ion-selective as well as more energy efficient for low-salinity desalination compared to techniques such as RO. Unlike IER or RO methods, CDI removes ions with electric fields, taking advantage of the inherently charged ions, which would naturally be attracted to the charged porous electrodes and thus separating them from the feed water. Description: LLNL researchers have developed a novel technique of flow-through electrode capacitive deioinization (FTE-CDI) which can be tailored for selective ion removal from water. It uses porous carbon aerogel materials as capacitive deionization (CDI) electrodes to selectively remove scale forming divalent ions (e.g., magnesium, calcium) from ""hard"" waters. Through precise control of electrode material synthesis conditions, both a high sorption capacity and a micropore-size distribution is achieved allowing for selective removal of divalent cations. The researchers have been able to demonstrate that their innovative system is capable of achieving an adsorption selectivity of calcium over sodium of more than two-fold. The selectivity can be reversed to favor monovalent ions over divalent ions by changing the electrode synthesis conditions. Advantages/Benefits:� Water softening with CDI eliminates the need for consumable chemicals and the downstream water treatment requirements.� Unlike the conventional reverse osmosis method, LLNL�s invention enables ion selectivity (e.g., able to favor removal of divalent ions such as magnesium and calcium in the presence of monovalent ions such as sodium).�� CDI is also potentially more energy efficient when compared to reverse osmosis. Water softening is performed with inherently low salinity feed water, and thus aligns well with the strengths of CDI. Potential Applications:� Water softening: applicable for commercial and residential systems, both of which have large existing markets where barriers to entry are potentially lower as compared to existing desalination/RO. Development Status:� Current stage of technology development:� TRL-3 LLNL has filed for patent protection on this invention. U.S. Patent Application No. 2021/0061683 Selective Removal of Scale-Forming Ions For Water Softening published 3/4/2021 LLNL is seeking industry partners with a demonstrated ability to bring such inventions to the market. Moving critical technology beyond the Laboratory to the commercial world helps our licensees gain a competitive edge in the marketplace. All licensing activities are conducted under policies relating to the strict nondisclosure of company proprietary information.� Note:� THIS IS NOT A PROCUREMENT.� Companies interested in commercializing LLNL's water softening using flow through electrode capacitive deionization should provide an electronic OR written statement of interest, which includes the following: Company Name and address. The name, address, and telephone number of a point of contact. A description of corporate expertise and/or facilities relevant to commercializing this technology. Please provide a complete electronic OR written statement to ensure consideration of your interest in LLNL's water softening using flow through electrode capacitive deionization. The subject heading in an email response should include the Notice ID and/or the title of LLNL�s Technology/Business Opportunity and directed to the Primary and Secondary Point of Contacts listed below. Written responses should be directed to: Lawrence Livermore National Laboratory Innovation and Partnerships Office P.O. Box 808, L-779 Livermore, CA� 94551-0808 Attention:�� Il-13462
 
Web Link
SAM.gov Permalink
(https://sam.gov/opp/2af5378e58d340e7bbfd3473c4da02ba/view)
 
Place of Performance
Address: Livermore, CA, USA
Country: USA
 
Record
SN06855990-F 20231012/231010230119 (samdaily.us)
 
Source
SAM.gov Link to This Notice
(may not be valid after Archive Date)

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